Listen
Definite listen if you like The Dark Knight Rises. Even if not, the banter between Matt and "guest host" Ben De Bono might be enough.
Batman Month
All the episodes in the month around The Dark Knight Rises premiere were on Batman.
Essential
The first iconic episode and a classic example of the intersection between pop culture and Christianity that the SFC does so well.
Skip
Discussion is not bad at all, but probably only listen if you loved the movie and want to hear the quick initial thoughts.
Skip
It's a clip show, so all the clips are already archived with their respective episodes.
Listen
Don't listen for the actual movie predictions (although those are fun), listen for the zaniness.
Skip
No need to listen to old news. Check the guide for what's interesting in hindsight.