All the episodes in the month around The Dark Knight Rises premiere were on Batman.
Definite listen if you like The Dark Knight Rises. Even if not, the banter between Matt and "guest host" Ben De Bono might be enough.
The first iconic episode and a classic example of the intersection between pop culture and Christianity that the SFC does so well.
Discussion is not bad at all, but probably only listen if you loved the movie and want to hear the quick initial thoughts.
It's a clip show, so all the clips are already archived with their respective episodes.
Don't listen for the actual movie predictions (although those are fun), listen for the zaniness.
No need to listen to old news. Check the guide for what's interesting in hindsight.